NEET 2026 ALL Q #1989
COMPETENCY BASED
APPLY
4 Marks 2026 NTA-RE-NEET-2026 MCQ SINGLE
Match the species in List-I with their geometry in List-II.
List-I:
A. $PCl_{5}$
B. $BrF_{5}$
C. $BF_{4}^{-}$
D. $[Ni(CN)_{4}]^{2-}$
List-II:
I. Tetrahedral
II. Square Planar
III. Trigonal bipyramidal
IV. Square pyramidal
Choose the correct answer from the options given below:
(A) A-III, B-II, C-I, D-IV
(B) A-IV, B-III, C-I, D-II
(C) A-III, B-IV, C-I, D-II
(D) A-III, B-I, C-II, D-IV
Correct Answer: C

AI Tutor Explanation

Powered by Gemini

Detailed Solution

Step 1: Analyze $PCl_{5}$

The central atom Phosphorus has 5 valence electrons and forms 5 bonds with Chlorine atoms. Using VSEPR theory, the steric number is 5 ($sp^{3}d$ hybridization), which corresponds to a Trigonal bipyramidal geometry (A-III).

Step 2: Analyze $BrF_{5}$

Bromine has 7 valence electrons. It forms 5 bonds with Fluorine and has 1 lone pair. The steric number is 6 ($sp^{3}d^{2}$ hybridization). With 5 bond pairs and 1 lone pair, the geometry is Square pyramidal (B-IV).

Step 3: Analyze $BF_{4}^{-}$

Boron has 3 valence electrons. In $BF_{4}^{-}$, it forms 4 bonds. The steric number is 4 ($sp^{3}$ hybridization), which corresponds to a Tetrahedral geometry (C-I).

Step 4: Analyze $[Ni(CN)_{4}]^{2-}$

Nickel is in the +2 oxidation state ($d^{8}$ configuration). $CN^{-}$ is a strong field ligand, causing pairing of electrons. This results in $dsp^{2}$ hybridization, which corresponds to a Square planar geometry (D-II).

Final Answer: A-III, B-IV, C-I, D-II

AI generated content. Review strictly for academic accuracy.

Pedagogical Audit
Bloom's Analysis: This is an APPLY question because the student must apply VSEPR theory and Valence Bond Theory principles to determine the molecular geometry of diverse chemical species.
Knowledge Dimension: PROCEDURAL
Justification: The student must follow a specific algorithmic process (calculating steric number, identifying hybridization, and accounting for lone pairs) to arrive at the correct structural classification.
Syllabus Audit: In the context of NEET, this is classified as COMPETENCY. This question tests the ability to integrate knowledge of Chemical Bonding and Coordination Chemistry, which is a high-yield area for competitive medical entrance exams.

More from this Chapter

MCQ_SINGLE
Given below are two statements: Statement I: Modern Homo sapiens arose in Australia and moved across continents. Statement II: Homo sapiens arose around 75000 to 10000 years ago. In the light of the above statements, choose the most appropriate answer from the options given below:
MCQ_SINGLE
Match List-I with List-II. List-I: A. Family B. Genus C. Class D. Phylum E. Order List-II: I. Sapindales II. Dicotyledonae III. Anacardiaceae IV. Angiospermae V. Mangifera Choose the correct answer from the options given below :
MCQ_SINGLE
For a salt XY, which is a strong electrolyte, the plot of $\Lambda_{m}$ versus $\sqrt{c}$ has a slope of $-90.0~S~cm^{2}mol^{-3/2}L^{1/2}$ at 298 K. At 0.01 M concentration of XY, the value of $\Lambda_{m}$ is $145.0~S~cm^{2}mol^{-1}$. The limiting molar conductivity of $Y^{-}$ ion $(\lambda_{Y^{-}}^{0}$, in $S~cm^{2}~mol^{-1}$) at 298 K will be (Given : $\lambda_{X^{+}}^{0}=74.0~S~cm^{2}mol^{-1})$
MCQ_SINGLE
Match List-I with List-II. List-I: A. Transformation B. Cloning site C. Selection D. Ori List-II: I. Restriction enzyme II. Transfer DNA to host bacteria III. Replication IV. Antibiotic Choose the correct answer from the options given below:
MCQ_SINGLE
Three identical p-n junction diodes $D_{1}$, $D_{2}$ and $D_{3}$ are connected across a battery as shown in the figure. If the width of the depletion regions of $D_{1},$ $D_{2}$ and $D_{3}$ are $W_{1},$ $W_{2}$ and $W_{3}$, respectively, then the correct option is: [Image Placeholder]
View All Questions