Transition metals (d-block elements) exhibit high melting points due to strong interatomic metallic bonding. This bonding arises from the overlap of d-orbitals, which provides a greater number of electrons for delocalization compared to s-block elements.
The reason states that 3d-electrons are involved in metallic bonding in addition to 3s-electrons. This is factually incorrect. In 3d transition metals, the valence shell is 4s, not 3s. The metallic bonding involves the participation of (n-1)d and ns electrons. Specifically, for the first transition series, it is the 3d and 4s electrons that contribute to the metallic bond strength.
Since the Assertion is correct regarding the high melting points, but the Reason incorrectly identifies the electron shells involved (citing 3s instead of 4s), the Reason is false.
Final Answer: D
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