Class NEET 2026 ALL Q #1948
COMPETENCY BASED
APPLY
4 Marks 2026 NTA-RE-NEET-2026 MCQ SINGLE
The formula of tetraammineaquachloridocobalt(III) chloride is
(A) $[Co(NH_{3})_{4}(H_{2}O)Cl]Cl_{2}$
(B) $[Co(NH_{3})_{4}Cl_{2}]Cl\cdot H_{2}O$
(C) $[Co(NH_{3})_{4}]Cl_{3}\cdot H_{2}O$
(D) $[Co(NH_{3})_{4}(H_{2}O)Cl]Cl$
Correct Answer: A

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Detailed Solution

Step 1: Identify the central metal and oxidation state

The central metal is Cobalt (Co) with an oxidation state of +3. This is indicated by (III) in the name.

Step 2: Identify the ligands and their charges

The ligands are:

  • Tetraammine: 4 $NH_{3}$ (neutral, charge = 0)
  • Aqua: 1 $H_{2}O$ (neutral, charge = 0)
  • Chlorido: 1 $Cl^{-}$ (anionic, charge = -1)

Step 3: Calculate the charge of the coordination sphere

The total charge of the complex ion is the sum of the metal oxidation state and the charges of the ligands: $$Charge = (+3) + 4(0) + 1(0) + 1(-1) = +2$$ Thus, the coordination sphere is $[Co(NH_{3})_{4}(H_{2}O)Cl]^{2+}$.

Step 4: Balance with counter ions

Since the complex ion has a charge of +2, we need two chloride ions ($Cl^{-}$) outside the coordination sphere to balance the charge. The formula is $[Co(NH_{3})_{4}(H_{2}O)Cl]Cl_{2}$.

Final Answer: [Co(NH_{3})_{4}(H_{2}O)Cl]Cl_{2}

AI Suggestion: Option A

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Pedagogical Audit
Bloom's Analysis: This is an APPLY question because the student must translate IUPAC nomenclature rules into a chemical formula by applying coordination chemistry principles.
Knowledge Dimension: PROCEDURAL
Justification: The student follows a specific algorithmic process (identifying ligands, calculating oxidation states, and balancing charges) to derive the correct chemical formula.
Syllabus Audit: In the context of NEET, this is classified as COMPETENCY. IUPAC nomenclature of coordination compounds is a high-frequency topic in the NEET chemistry syllabus, requiring precision in applying rules of coordination chemistry.

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