Class NEET 2026 ALL Q #1949
COMPETENCY BASED
APPLY
4 Marks 2026 NTA-RE-NEET-2026 MCQ SINGLE
The lanthanide ion having four unpaired electrons is (Given: Atomic numbers of $Ce=58$, $Nd=60$, $Tb=65$ and $Ho=67$)
(A) $Ho^{3+}$
(B) $Nd^{3+}$
(C) $Ce^{3+}$
(D) $Tb^{3+}$
Correct Answer: A

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Detailed Solution

Step 1: Determine Electronic Configurations

The general electronic configuration of lanthanides is $[Xe] 4f^{n} 5d^{0-1} 6s^{2}$. When forming $3+$ ions, the two $6s$ electrons and one $4f$ or $5d$ electron are removed.

Step 2: Analyze each option

We calculate the $4f$ electrons for each ion:

(A) $Ho^{3+}$ ($Z=67$): Neutral $Ho$ is $[Xe] 4f^{11} 6s^{2}$. $Ho^{3+}$ is $[Xe] 4f^{10}$. Unpaired electrons = $14 - 10 = 4$ (in the second half of the shell).

(B) $Nd^{3+}$ ($Z=60$): Neutral $Nd$ is $[Xe] 4f^{4} 6s^{2}$. $Nd^{3+}$ is $[Xe] 4f^{3}$. Unpaired electrons = 3.

(C) $Ce^{3+}$ ($Z=58$): Neutral $Ce$ is $[Xe] 4f^{1} 5d^{1} 6s^{2}$. $Ce^{3+}$ is $[Xe] 4f^{1}$. Unpaired electrons = 1.

(D) $Tb^{3+}$ ($Z=65$): Neutral $Tb$ is $[Xe] 4f^{9} 6s^{2}$. $Tb^{3+}$ is $[Xe] 4f^{8}$. Unpaired electrons = $8 - 7 = 1$ (or 6 depending on orbital filling, but not 4).

Step 3: Conclusion

The ion $Ho^{3+}$ has a $4f^{10}$ configuration. According to Hund's rule, filling 10 electrons in 7 orbitals results in 4 unpaired electrons.

Final Answer: Ho^{3+}

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Pedagogical Audit
Bloom's Analysis: This is an APPLY question because the student must apply the principles of electronic configuration and Hund's rule to specific lanthanide ions.
Knowledge Dimension: PROCEDURAL
Justification: The student follows a specific algorithmic process (configuration -> ionization -> orbital filling) to reach the result.
Syllabus Audit: In the context of NEET, this is classified as COMPETENCY. It tests the ability to handle d-block and f-block element properties beyond rote memorization.