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A relation $R$ is reflexive if $a R a$ for all $a \in A$. Here, $a R a$ means a is a brother of a. Since a person cannot be their own brother, the relation is not reflexive.
A relation $R$ is symmetric if $a R b \implies b R a$. If a is a brother of b, then b must also be a brother of a. Thus, the relation is symmetric.
An equivalence relation must be reflexive, symmetric, and transitive. Since the relation fails the reflexivity test, it cannot be an equivalence relation.
Final Answer: (i) No, (ii) Yes, (iii) No
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