Class CBSE Class 12 Chemistry Chemical Kinetics Q #1889
COMPETENCY BASED
APPLY
1 Marks 2005 SNP VSA
Find out the rate constant for the reaction $\text{C(s)} + \text{O}_2\text{(g)} \rightarrow \text{CO}_2\text{(g)}$

AI Tutor Explanation

Powered by Gemini

Detailed Solution

Step 1: Analyze the Reaction Type

The given reaction is a heterogeneous reaction involving a solid reactant C(s) and a gaseous reactant O2(g). In chemical kinetics, the rate of reaction depends on the concentration of species in the gaseous or aqueous phase.

Step 2: Apply the Rate Law

For the reaction C(s) + O2(g) → CO2(g), the rate law is expressed as: $$Rate = k[O_2]^1$$ The concentration of the solid C(s) is taken as unity (constant) and is incorporated into the rate constant.

Step 3: Determine the Rate Constant

The rate constant k cannot be determined solely from the chemical equation without experimental data (initial concentration and rate at a specific time). It is defined by the Arrhenius equation: $$k = Ae^{-E_a/RT}$$ Where A is the frequency factor, Ea is the activation energy, R is the gas constant, and T is the temperature.

Final Answer: The rate constant k is determined experimentally using the Arrhenius equation k = Ae^{-E_a/RT} and cannot be calculated from the stoichiometry of the reaction alone.

AI generated content. Review strictly for academic accuracy.

Pedagogical Audit
Bloom's Analysis: This is an APPLY question because the student must apply the principles of chemical kinetics and the Arrhenius equation to a specific reaction scenario.
Knowledge Dimension: PROCEDURAL
Justification: The student must follow the procedure of identifying that rate constants are experimental parameters rather than stoichiometric ones.
Syllabus Audit: In the context of CBSE Class 12, this is classified as COMPETENCY. This question tests the conceptual understanding that rate constants are temperature-dependent experimental values, not derived from balanced chemical equations.

More from this Chapter

No other questions found.