The number of elements in the set $\left\{n \in \mathbb{N}: 10 \leq n \leq 100\right.$ and $3^{n}-3$ is a multiple of 7$\}$ is ___________.

Among the relations $S = {(a, b) : a, b \in R - {0}, 2 + \frac{a}{b} > 0}$ and $T = {(a, b) : a, b \in R, a^2 - b^2 \in Z}$,

In a survey of 220 students of a higher secondary school, it was found that at least 125 and at most 130 students studied Mathematics; at least 85 and at most 95 studied Physics; at least 75 and at most 90 studied Chemistry; 30 studied both Physics and Chemistry; 50 studied both Chemistry and Mathematics; 40 studied both Mathematics and Physics and 10 studied none of these subjects. Let $m$ and $n$ respectively be the least and the most number of students who studied all the three subjects. Then $\mathrm{m}+\mathrm{n}$ is equal to ___________.

4 Let $A=\{1,2,3\}$. The number of relations on $A$, containing $(1,2)$ and $(2,3)$, which are reflexive and transitive but not symmetric, is _________.

Consider the relations $R_1$ and $R_2$ defined as $aR_1b \Leftrightarrow a^2 + b^2 = 1$ for all $a, b \in R$ and $(a, b)R_2(c, d) \Leftrightarrow a+ d = b + c$ for all $(a, b), (c, d) \in N \times N$. Then: